Every binary market has a Yes share and a No share that should always add up to exactly $1.00, since one of them is guaranteed to be worth $1 at resolution. When the two prices instead add up to more than $1.00, you sell both sides (or short the overpriced pair) and pocket the difference no matter how the event turns out. The profit is locked in the moment you fill both legs; it just takes patience to hold until the market resolves.
Markets on Polymarket where yes/no complement arbitrage is the natural play: